Determination of the Chemical Composition of Banana Leaves Wax

Authors

  • Kaana Asemave Dept. Chemistry, Benue State University, Makurdi - Nigeria
  • Stephen Anthony Ujah Dept. Chemistry, Benue State University, Makurdi - Nigeria

Keywords:

Agricultural residues, Banana Wax, Palmitic acid, Linoleic acid

Abstract

Banana cultivation generates an enormous number of agricultural residues, such as pseudo-stems and leaves. These residues are regarded as an unutilized sustainable biomass resource. Hence the research considers extraction of banana leaves wax and its characterization. Soxhlet apparatus was used for the extraction and a yield of 0.97wt% was found. Thereafter, solubility, FTIR, GC-MS, and UV/visible analyses were performed on the wax. The wax was soluble in hexane and ethyl acetate but insoluble in methanol and ethanol. The FTIR absorption peaks of 3373.2-3384.4, 2922.2-2851.4, 1738.9-1666.1 cm­-1 implied the presence of alcohol, saturated organic compounds, and then ester/aldehyde/ketones/carboxylic acid, respectively. The ?max for the wax was found at 360 nm.  The second absorption was found at 400 nm. These results indicate the presence of unsaturated compounds. Thus, the wax contains long chain alkanes, alcohols, esters, aldehydes and carboxylic acids. However, the predominant groups of chemicals present in the wax are palmitic acid (C16), linoleic acid (C18); lesser amounts of esters, alcohols, aldehydes, and alkanes. The banana wax can be used in making cosmetics, inks, candles, packaging materials and so on.

References

. N. V. Phirke, R. P. Patil, S. B. Chincholkar, and R. M. Kothari, “Recycling of banana pseudostem waste for economical production of quality banana,” Resour. Conserv. Recycl., vol. 31, pp. 347–353, 2001.

. N. Cordeiro, M. N. Belgacem, I. C. Torres, and J. C. V. P. Moura, “Chemical composition and pulping of banana pseudo-stems,” Ind. Crop. Prod., vol. 19, pp. 147–154, 2004.

. J. B. Ulloa, J. H. van Weerd, E. A. Huisman, and J. A. J. Verreth, “Tropical agricultural residues and their potential uses in fish feeds: the Costa Rican situation,” Waste Manag., vol. 24, pp. 87–97, 2004.

. T. YANAGIDA, N. SHIMIZU, and T. KIMURA, “Extraction of Wax from Banana Leaves as an Alternative Way of Utilizing Agricultural Residues,” Japan J. Food Eng., vol. 61, pp. 29–35, 2005.

. S. Charumanee, S. Yotsawimonwat, P. Sirisa-ard, and K. Pholsongkram, “Characterization and chemical composition of epicuticular wax from banana leaves grown in Northern Thailand,” Songklanakarin J. Sci. Technol., vol. 39, no. 4, pp. 509–516, 2017.

. P. Kolattukudy, “Cutin, suberin and waxes,” in Lipids: structure and function, P. K. Stumpf, Ed. New York, Academic Press, 1980, pp. 571–646.

. L. Kunst and A. Samuels, “Biosynthesis and Secretion of Plant Cuticular Wax,” Prog. Lipid Res., vol. 42, pp. 51–80, 2003.

. S. Pashova, “Plant waxes – nature, types and application. Excellence In Business, Commodity Science and Tourism, Bucharest Academy Of Economic Studies, Faculty of Commerce,” Forum Ware Int. Spec. Issue, pp. 166–170, 2001.

. M. Chughtai and S. Khan., “No Title,” Pakistan J. Sci., vol. 23, p. 61, 1971.

. W. Christie, Lipid Analysis, (3rd edition). 2003.

. J. W. T. Huat, “Extraction of Wax from Plants for Possible Commercial Application,” Universiti Malaysia Saraw Ak, 2013.

. J. R. Dodson et al., “Bio-derived materials as a green route for precious & critical metal recovery and re-use,” Green Chem. (RSC), pp. 1–15, 2015.

. K. Asemave and T. A. Asemave, “African Shea Butter as a Staple and Renewable Bioproduct,” Int. J. Sci. Res., vol. 4, no. 12, pp. 2133–2135, 2015.

. K. Asemave, F. P. Byrne, J. H. Clark, T. J. Farmer, and A. J. Hunt, “Modification of bio-based β-diketone from wheat straw wax: synthesis of polydentate lipophilic super-chelators for enhanced metal recovery,” RSC Adv., vol. 9, no. 7, 2019.

. K. Asemave and T. T. Anure, “The bioactivities of the neem (seeds, leaves and their extracts) against Callosobruchus maculatus on Vigna Subterranean L,” Prog. Chem. Biochem. Res., vol. 2, no. 3, pp. 92–98, 2019.

. K. Asemave, “Bioactivity of Arachis Hypogaea Shell Extracts against Staphylococcus aureus and Pseudomonas aeruginosa,” Prog. Chem. Biochem. Res., vol. 4, no. 3, pp. 331–336, 2021.

. T. Yanagida, N. Shimizu, and T. Kimura, “Extraction of wax and functional compounds from fresh and dry banana leaves,” Japan J. Food Eng., vol. 6, no. 1, pp. 79–87, 2005.

. T. Attard, “Supercritical CO2 extraction of waxes as part of a holistic biorefinery,” University of York, 2015.

. M. Riederer and L. Schreiber, “Protecting against water loss: Analysis of the barrier properties of plant cuticles,” J. Exp. Bot., vol. 52, no. 363, pp. 2023–2032, 2001.

. R. Hamilton, Waxes: Chemistry, Molecular Biology and Functions. Dundee: The Oily Press, 1995.

. E. H. K. Sin, “The extraction and fractionation of waxes from biomass,” University of York, 2012.

. T. Yanagida, N. Shimizu, and T. Kimura, “Extraction of wax from banana as an alternative way of utilizing agricultural residues,” Japan J. Food Eng., vol. 6, no. 1, pp. 29–35, 2005.

. K. Asemave, “Biobased Lipophilic Chelating Agents and their Applications in Metals Recovery,” University of York, UK, 2016.

. K. Asemave, Supplement of Inorganic Kinetics: Substitution Reaction of Cobalt (III) with Amino acids, First. Saarbrücken, Germany: LAP LAMBERT Academic Publishing, 2012.

. K. Asemave, S. G. Yiase, and S. O. Adejo, “Kinetics and Mechanism of Substitution Reaction of Trans-Dichloro-bis-(Ethylenediammine) Cobalt (III) Chloride with Cysteine, Aspartic acid and Phenylalanine,” Int. J. Sci. Technol., vol. 2, no. 5, pp. 242–247, 2012.

. K. Asemave, S. G. Yiase, S. O. Adejo, and B. A. Anhwange, “Substitution Reaction of trans-dichloro-bis-(ethylenediamine) Cobalt (III) Chloride and Phenylalanine-A Kinetics and Mechanism Study,” Int. J. Mod. Chem, vol. 1, no. 2, pp. 93–101, 2012.

. K. ASEMAVE, S. G. YIASE, S. O. ADEJO, and B. A. ANHWANGE, “KINETICS AND MECHANISM OF SUBSTITUTION REACTION OF trans-DICHLOROBIS (ETHYLENEDIAMMINE) COBALT (III) CHLORIDE WITH ASPARTIC ACID,” Int. J. Inorg. Bioinorg. Chem., vol. 2, no. 1, pp. 11–14, 2011.

. K. Asemave, S. Yiase, and S. O. Adejo, “Kinetics and Mechanism of Substitution Reaction of Trans-Dichloro-bis-(Ethylenediammine) Cobalt (III) Chloride with Cysteine, Aspartic acid and Phenylalanine,” Int. J. Sci. Technol., vol. 2, no. 5, pp. 242–247, 2012.

. K. Asemave, S. G. Yiase, and S. O. Adejo, “Kinetics and Mechanism of Substitution Reaction of trans-Dichlorobis (ethylenediammine) cobalt (III) chloride with Cysteine,” Int. J. Mod. Org. Chem, vol. 1, no. 1, pp. 1–9, 2012.

. K. Asemave, S. G. Yiase, S. O. Adejo, and B. A. Anhwange, “Kinetics and Mechanism of Substitution Reaction of trans-dichloro-bis-(ethylenediammine) cobalt (III) chloride with Aspartic acid,” Int. J. Inorg. Bioinorg. Chem., vol. 2, no. 1, pp. 11–14, 2011.

. K. Asemave, B. Anhwange, and U. J. Ahile, “Hydrolysis of Fatty Esters in Dichloromethane/ Methanol,” FUW Trends Sci. Technol. J., vol. 2, no. 1B, pp. 521–524, 2017.

. P. R. REDDY, M. RADHIKA, and P. MANJULA, “Synthesis and characterization of mixed ligand complexes of Zn(II) and Co(II) with amino acids: Relevance to zinc binding sites in zinc fingers,” J. Chem. Sci., vol. 117, no. 3, pp. 239–246, 2005.

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Published

2021-10-03

How to Cite

Asemave, K. ., & Ujah, S. A. . (2021). Determination of the Chemical Composition of Banana Leaves Wax. International Journal of Applied Sciences: Current and Future Research Trends, 11(1), 23–30. Retrieved from https://ijascfrtjournal.isrra.org/index.php/Applied_Sciences_Journal/article/view/1132

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